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In the title compound, [CuBr(C(13)H(12)N(2)S)(2)]·H(2)O, the Cu(I) atom adopts a slightly distorted trigonal-planar coordination arising from two S atoms of two diphenyl-thio-urea ligands and a bromide ion. There are two intra-molecular N-H⋯Br hydrogen bonds completing twisted six-membered rings with R(6) motifs. The dihedral angles between the aromatic rings in the ligands are 62.11 (13) and 85.73 (13)°. In the crystal, components are linked by N-H⋯O, O-H⋯S and O-H⋯π inter-actions. There also exist π-π inter-actions with a distance of 3.876 (2) Å between the centroids of benzene rings of two different ligands. Together, the inter-molecular inter-actions lead to a three-dimensional network.

Bromidobis(N,N′-diphenylthiourea-κS)copper(I) monohydrate