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In the crystal structure of the title compound, [Cu 2 (CH 3 COO) 4 (C 9 H 7 N) 2 ], the Cu II  cation is coordinated by four acetate anions and one isoquinoline mol­ecule in a distorted square-pyramidal geometry; the Cu II  cation is 0.1681 (6) Å from the basal coordination plane formed by the four O atoms. Each acetate anion bridges two Cu II  cations to form the centrosymmetric dinuclear complex. Within the dinuclear mol­ecule, the Cu⋯Cu separation is 2.6459 (4) Å. A parallel arrangement of isoquinoline ligands of adjacent complexes is observed in the crystal structure; the face-to-face distance of 3.610 (10) Å suggests there is no π–π stacking between isoquinoline ring systems.

Tetra-μ2-acetato-κ8O:O′-bis[(isoquinoline-κN)copper(II)]

Tetra-μ₂-acetato-κ⁸O:O′-bis[(isoquinoline-κN)copper(II)]