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In the title compound, [Cu(C 14 H 12 N 2 O 4 )(C 36 H 28 OP 2 )]PF 6 ·CH 3 CN, the  Cu(I) ion is coordinated by two N atoms from the dimethyl 2,2′-biphenyl-4,4′-dicarboxyl­ate ligand and two P atoms from the bis­[2-(diphenyl­phosphino)phen­yl] ether ligand in a distorted tetra­hedral environment. In the cation, the short distance of 3.870 (4) Å between the centroids of the benzene and phenyl rings suggests the existence of intra­molecular π–π inter­actions.

acta crystallographica. section e

{Bis[2-(diphenylphosphino)phenyl] ether-κ2P:P′}(dimethyl 2,2′-biphenyl-4,4′-dicarboxylate-κ2N:N′)copper(I) hexafluoridophosphate acetonitrile solvate