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In the title compound, [Co(C 16 H 14 N 4 O) 2 ](C 6 H 2 N 3 O 7 ) 2 ·3CH 3 CN, the Co II  ion is located on a crystallographic twofold rotation axis and is coordinated in a slightly distorted tetra­hedral environment by four N atoms from the two bidentate  N -heterocycles. The crystal structure is stabilized by inter­molecular N—H⋯O and N—H⋯N hydrogen bonds. One of the acetonitrile solvent mol­ecules also lies on a twofold rotation axis.

Bis[1,3-bis(benzimidazol-2-yl)-2-oxapropane]cobalt(II) dipicrate acetonitrile trisolvate