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The mol­ecule of the title binuclear copper(II) complex, [Cu 2 (CH 3 COO) 4 (C 5 H 5 NO) 2 ], occupies a special position on a crystallographic inversion centre; the coordination environment of the Cu II  atom is slightly distorted square-pyramidal and is made up of four O atoms belonging to four acetate groups in the basal plane with the O atom of pyridine  N -oxide ligand in the apical position. The Cu—Cu distance is 2.6376 (6) Å.

Tetra-μ-acetato-bis[(pyridineN-oxide)copper(II)](Cu—Cu)