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The title compound, [Sn(C 6 H 5 ) 3 (C 17 H 25 O 3 S)]  n  , comprises two symmetry-independent five-coordinated triphenyl­tin mol­ecules which are linked by carboxyl­ate bridges into a polymeric chain. The Sn IV  atom is in a distorted  trans -C 3 SnO 2  trigonal-bipyramidal geometry. The presence of two bulky  tert -butyl groups on the benzene ring prevents any hydrogen-bonding inter­actions involving the hydroxyl substituents.

catena-Poly[[triphenyltin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetato-κ2O:O′]

catena-Poly[[triphenyltin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetato-κ²O:O′]