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The title mixed-ligand oxidovanadium(IV) compound, [VO(C 5 H 7 O 2 ) 2 (C 8 H 9 N 3 )], contains a V IV  atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the  N -heterocyclic ligand are  cis  to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intra­molecular hydrogen bonds between the  exo -NH 2  group H atoms and acetyl­acetonate O atoms stabilize the crystal structure.

Bis(acetylacetonato-κ2O,O′)(2-amino-1-methyl-1H-benzimidazole-κN3)oxidovanadium(IV)

Bis(acetylacetonato-κ²O,O′)(2-amino-1-methyl-1H-benzimidazole-κN³)oxidovanadium(IV)