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Reaction of 4′-phenyl-2,2′:6′,2′′-terpyridine (phtpy), copper acetate hydrate and ammonium thio­cyanate under solvothermal conditions led to the formation of the title compound, {[Cu(C 21 H 15 N 3 ) 2 ][Cu 2 (NCS) 4 ]}  n  . The structure is composed of discrete [Cu(phtpy) 2 ] 2+  cations and polymeric anionic {[Cu(SCN) 2 ] − } chains propagating along [010]. The central Cu 2+  ion in the cation is coordinated by two tridentate chelating phtpy ligands in a distorted octa­hedral geometry. In each of the two crystallographically independent centrosymmetric anions, the Cu I  atoms are bridged in a 1,3-μ 2 -bridging mode by two S and two N atoms, resulting in a distorted tetrahedral CuN 2 S 2  coordination. The [Cu(phtpy) 2 ] 2+  cations are fixed between these polymers by inter­molecular C—H⋯S hydrogen bonds.

acta crystallographica section e structure reports online

catena-Poly[hemi[bis(4′-phenyl-2,2′:6′,2′′-terpyridine-κ3N)copper(II)] [cuprate(I)-di-μ2-thiocyanato-κ2N:S;κ2S:N]]