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In the title compound, [Ni(C 12 H 16 NO 5 ) 2 ]·2H 2 O, the Ni II  atom is coordinated by four O atoms and two N atoms from the two 6-meth­oxy-2-{[tris­(hydroxy­meth­yl)meth­yl]imino­meth­yl}phenolate ligands in a distorted octa­hedral coordination geometry. O—H⋯O hydrogen bonds link the complexes and uncoordinated water mol­ecules into two-dimensional networks parallel to (001).

Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl-κO]iminomethyl}phenolato-κ2N,O1)nickel(II) dihydrate

Bis(6-methoxy-2-{[tris(hydroxymethyl)methyl-κO]iminomethyl}phenolato-κ²N,O¹)nickel(II) dihydrate