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In the title compound, [Fe(CH 3 CN) 2 (C 14 H 32 O 4 P 2 ) 2 ]Cl 2 , the Fe II  atom lies on a crystallographic inversion center and has a distorted  trans -FeN 2 P 4  octa­hedral coordination environment arising from two  P , P ′-bidentate 1,2-bis­[bis­(3-hydroxy­prop­yl)phosphino]ethane ligands in the equatorial plane and two acetonitrile mol­ecules in the axial positions. One of the pendant –(CH 2 ) 3 OH groups of the ligand is disordered over two sets of sites in a 0.597 (5):0.403 (5) ratio. In the crystal, O—H⋯Cl and O—H⋯O hydrogen bonding helps to establish the packing.

trans-Bis(acetonitrile-κN)bis{1,2-bis[bis(3-hydroxypropyl)phosphino]ethane-κ2P,P′}iron(II) dichloride

trans-Bis(acetonitrile-κN)bis{1,2-bis[bis(3-hydroxypropyl)phosphino]ethane-κ²P,P′}iron(II) dichloride