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In the title chromium silanethiol­ate, [Cr(C 12 H 27 O 3 SSi) 2 (C 7 H 9 N) 2 ]·C 7 H 8 , the Cr II  atom is coordinated by two S and two N atoms in a distorted square-planar geometrical arrangement. The mononuclear mol­ecule lies on a twofold axis that passes through the pyridine N atoms. The toluene solvent mol­ecule is equally disordered about a twofold axis.

Bis(3,5-dimethylpyridine-κN)bis(tri-tert-butoxysilanethiolato-κS)chromium(II) toluene solvate