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The asymmetric unit of the polymeric title compound, [Na 2 (C 20 H 13 O 5 P)(C 2 H 6 O)(H 2 O) 5 ]  n  , consists of two Na I  ions, one 2′-hydr­oxy-1,1′-binaphthyl-2-yl phosphate anion, one ethanol ligand and  five water molecules of crysallization. Each Na I  ion has a distorted octa­hedral coordination geometry. The phosphate anion coordinates to one Na I  ion and the ethanol mol­ecule coordinates to the other. The five water mol­ecules bridge the Na I  ions, forming an inorganic chain structure along the  b  axis. The chains are connected by O—H⋯O hydrogen bonds into an organic–inorganic hybrid layer parallel to (001).

catena-Poly[[(ethanol-κO)sodium(I)]-di-μ-aqua-[(rac-2′-hydroxy-1,1′-binaphthyl-2-yl phosphato-κO)sodium]-tri-μ-aqua]