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The  N -oxide O atom of the minoxidil unit in the 1/1 adduct with lead(II) iodide, [PbI 2 (C 9 H 15 N 5 O)]  n  , bridges two Pb II  atoms, as do each of the I atoms. The bridging inter­actions give rise to a linear chain motif that propagates along the  a  axis of the ortho­rhom­bic unit cell. The  coordination sphere around the six-coordinate Pb II  atom is a distorted ψ-monocapped octa­hedron in which the stereochemically active lone pair caps one of the faces defined by the O and I atoms forming the longer Pb—O or Pb—I bonds. The Pb II  atom lies on a mirror plane; the mirror plane is perpendicular to the pyrimidine ring and it bis­ects the piperidine ring. The aromatic ring is disordered about the mirror plane with respect to the 1-nitro­gen and 5-carbon atoms.

catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidineN-oxide-κ2O:O]di-μ-iodido]

catena-Poly[lead(II)-[μ-2,4-diamino-6-(piperidin-1-yl)pyrimidineN-oxide-κ²O:O]di-μ-iodido]