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The relative stereochemistry of the title compound, C 20 H 23 NO 3 , was established by X-ray analysis. The asymmetric unit contains two independent mol­ecules. In the crystal structure, each type of mol­ecule forms a centrosymmetric dimer  via  pairs of inter­molecular O—H⋯O hydrogen bonds, resulting in an  R22 (10) loop in each case.

tert-ButylN-hydroxy-N-[(1S*,2R*)-2-(1-naphthyl)cyclopent-3-en-1-yl]carbamate

tert-ButylN-hydroxy-N-[(1S,2R)-2-(1-naphthyl)cyclopent-3-en-1-yl]carbamate