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In the title compound, C 11 H 15 N 32+ ·2Cl − ·H 2 O, one N atom of the imidazole ring and the N atom of the pyrrolidine ring are protonated. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring benzimidazole systems [centroid–centroid duistance = 3.712 (2) Å]. The crystal structure is further stabilized by inter­molecular N—H⋯Cl, O—H⋯Cl and N—H⋯O hydrogen bonds.

(S)-2-(2-Pyrrolidinio)-1H-benzimidazol-3-ium dichloride monohydrate