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There are two independent mol­ecules in the asymmetric unit of the title compound, C 13 H 23 NO 5 S. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link mol­ecules into two independent one-dimensional chains along [100]. The crystal studied was found to be a non-merohedral twin with a ratio of 0.615 (6):0.385 (1) for the refined components. At 200 (1) K [Singh  et al.  (2009  ▶ ).  Acta Cryst . E 65 , o1385–o1386] the crystal structure of the title compound contains one disordered mol­ecule in the asymmetric unit of a monoclinic unit cell.

Triclinic modification ofN-[(1,1-dimethylethoxy)carbonyl]-3-[(R)-prop-2-en-1-ylsulfinyl]-(R)-alanine ethyl ester at 120 (1) K