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The enanti­omerically pure title compound, C 12 H 16 ClNO 4 S 2 , contains a pyramidal N atom with an S—N bond length of 1.6306 (15) Å. Mol­ecules are linked to form chains parallel to the  a  axis by classical N—H⋯O hydrogen bonding involving a sulfonyl O atom, supported by three weak C—H⋯ X  inter­actions. ( X  = S, O).

(2S)-Methyl 2-(4-chlorobenzenesulfonamido)-4-(methylsulfanyl)butanoate