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The asymmetric unit of the title compound, [Ce(NCS) 3 (C 15 H 15 NO 2 ) 3 ], contains three Schiff base 2-methoxy-6-[(4-methyl­phenyl)iminometh­yl]­phenol (H L ) ligands and three independent thio­cyanate ions that coordinate the cerium ion  via  their N atoms. The protonated imine N atoms are involved in an intra­molecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine.

Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ2O,O′}tris(thiocyanato-κN)cerium(III)

Tris{2-methoxy-6-[(4-methylphenyl)iminiomethyl]phenolato-κ²O,O′}tris(thiocyanato-κN)cerium(III)