English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The microwave solvothermal reaction of nickel nitrate with trimesic acid provided the title compound, [Ni(3)(BTC)(2)(H(2)O)(12)](n) (BTC = benzene-1,3,5-tricarboxyl-ate anion, C(9)H(3)O(6)), which is a metal coordination polymer composed of one-dimensional zigzag chains. The crystal under investigation was ramecically twinned with an approximate twin domain ratio of 1:1. In the asymmetric unit, there are two types of Ni atoms. One of the NiO(6) groups (2 symmetry) is coordinated to only one carboxyl-ate group and thus terminal, the other is bridging, forming the coordination polymer. The extended chains are connected by the organic BTC anions via μ(2)-linkages. O-H⋯O hydrogen bonds and π-π inter-actions between the chains [centroid-centroid distance 3.58 (1) Å] induce the complex to mimic a three-dimensional structure.

acta crystallographica. section e

catena-Poly[[tetraaquanickel(II)]-μ3-benzene-1,3,5-tricarboxylato-3′:1:2-κ4O1:O3,O3′:O5-[tetraaquanickel(II)]-μ2-benzene-1,3,5-tricarboxylato-2:3κ2O1:O3-[tetraaquanickel(II)]]