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The title compound, C 4 H 12 NO 3+ ·C 2 HCl 2 O 2− , was obtained from dichloro­acetic acid and 2-amino-2-(hydroxy­meth­yl)propane-1,3-diol. In the crystal structure, the cations and anions are connected by inter­molecular N—H⋯O and O—H⋯O hydrogen bonding, forming a two-dimensional array parallel to (001). The crystal used for analysis was a merohedral twin, as indicated by the Flack parameter of 0.67 (6).

1,3-Dihydroxy-2-(hydroxymethyl)propan-2-aminium 2,2-dichloroacetate