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In the title mononuclear complex, [Zn(N 3 ) 2 (C 8 H 8 N 6 ) 2 ], the Zn II  atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa­hedral environment by four N atoms from two 2,4-diamino-6-(2-pyrid­yl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N—H⋯N hydrogen bonds between the ligand and azide ion link the complex mol­ecules into a three-dimensional network.

Diazidobis[2,4-diamino-6-(2-pyridyl)-1,3,5-triazine-κ2N1,N6]zinc(II)

Diazidobis[2,4-diamino-6-(2-pyridyl)-1,3,5-triazine-κ²N¹,N⁶]zinc(II)