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The asymmetric unit of the title compound, [Cd(C(6)H(11)Cl(2)NO(6)P(2))(H(2)O)(3)](n), contains two octahedrally coordinated Cd atoms located in special positions, one on a twofold rotation axis and the other on a centre of symmetry. The metal atoms are connected by methyl morpholino dichloro-methyl-enediphospho-nate ligands into chains in the c-axis direction. These chains are further connected by O-H⋯O hydrogen bonds into a layer-like construction along (100).

acta crystallographica. section e

catena-Poly[[diaquacadmium(II)]-μ-(methyl morpholino dichloromethylenediphosphonato)-κ3O,O′:O′′-[tetraaquacadmium(II)]-μ-(methyl morpholino dichloromethylenediphosphonato)-κ3O:O′,O′′]