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The mol­ecule of the title compound, [NaNi(C 18 H 18 N 2 O 4 )(C 2 N 3 )(H 2 O)], is approximately planar, with a maximum deviation from the mol­ecular plane of 0.770 (5) Å. The coordination environment of the Ni 2+  ion is distorted square-planar and it is N 2 O 2  coordinated by the 6,6′-dimeth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate Schiff base ligand. The Na +  atom is chelated by the four O atoms of the Schiff base ligand, a water ligand and a dicyanamide anion. The structure displays inter­molecular O—H⋯N hydrogen bonding.

Aqua(dicyanamido){μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)sodium