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The title compound, C 14 H 12 ClNO 3 ·0.25H 2 O, exists in the keto–amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)°. Bifurcated intra­molecular N—H⋯(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains. π–π contacts between benzene rings [centroid–centroid distance = 3.5065 (9) Å] may further stabilize the structure. There also exists a weak C—H⋯π inter­action.

(Z)-6-[(5-Chloro-2-hydroxyanilino)methylene]-4-methoxycyclohexa-2,4-dienone 0.25-hydrate