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In the title compound, [Ni(C(8)H(5)Cl(2)N(3)OS)(C(12)H(8)N(2))(CH(3)OH)], the Ni(II) atom is octa-hedrally coordinated by one N, one O and one S atom from a 3,5-dichloro-2-oxidobenzaldehyde thio-semicarbazonate ligand, another O atom from methanol and another two N atoms from 1,10-phenanthroline. The crystal structure is constructed by N-H⋯Cl, N-H⋯N, C-H⋯S and O-H⋯S hydrogen bonds.

acta crystallographica. section e

mer-(3,5-Dichloro-2-oxidobenzaldehyde thiosemicarbazonato-κ3S,N1,O)(methanol-κO)(1,10-phenanthroline-κ2N,N′)nickel(II)