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In the title mol­ecule, C 16 H 20 O 5 S 6 , the two five-membered rings form a dihedral angle of 4.7 (3)°. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds, which link the mol­ecules into chains propagating in [1    0], and π–π inter­actions, indicated by the short distances [3.756 (5) Å] between the centroids of five-membered rings from mol­ecules related by translation along the  b  axis.

Methyl 2,3-(3,6,9-trioxaundecane-1,11-diyldithio)-1,4,5,8-tetrathiafulvalene-6-carboxylate