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The title compound, C 17 H 24 NO 5 S + ·C 18 H 13 O 8− , is the key inter­mediate during the preparation of lesatropane [systematic name (1 R ,3 S ,5 R ,6 S )-6-acetoxy-3-(4-methylphenylsulfonyloxy)tropane], a potential anti­glaucoma agent. The tertiary N atom of the tropane ring is involved in inter­molecular N—H⋯O hydrogen bonding, and the carboxylate groups are involved in inter­molecular O—H⋯O hydrogen bonding.

acta crystallographica. section e

(1R,3S,5R,6S)-6-Acetoxy-8-methyl-3-(p-tolylsulfonyloxy)-8-azoniabicyclo[3.2.1]octane (2R,3R)-2,3-bis(benzoyloxy)-3-carboxypropanoate