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The title compound, [Zn(C 14 H 8 N 2 O 4 )(H 2 O) 2 ]  n  , consists of zigzag chains of Zn atoms bridged by azobenzene-4,4′-dicarboxyl­ate ligands. The Zn II  atom, lying on a twofold rotation axis, is coordinated by four O atoms from the carboxyl­ate groups and two water mol­ecules, giving rise to a considerably distorted octa­hedral coordination envionment. The ligand lies on an inversion center. In the crystal structure, π–π inter­actions between the ligands [inter­planar distance = 3.527 (3) Å] assemble the chains into a sheet-like structure. O—H⋯O hydrogen bonds between the coordinated water mol­ecules and carboxyl­ate O atoms connect the sheets into a three-dimensional network.

catena-Poly[[diaquazinc(II)]-μ-trans-4,4′-diazenediyldibenzoato-κ4O,O′:O′′,O′′′]

catena-Poly[[diaquazinc(II)]-μ-trans-4,4′-diazenediyldibenzoato-κ⁴O,O′:O′′,O′′′]