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The title complex, [Co 3 (C 8 H 3 NO 6 ) 2 (C 2 H 3 O 2 ) 2 (C 10 H 8 N 2 ) 2 (H 2 O) 2 ], was synthesized under hydro­thermal conditions. The structure features a centrosymmetric complex with three Co II  centres, one of which is located on a centre of inversion. The Co centres are coordinated in a distorted octa­hedral geometry. The bipyridine ligands are bonded to just one Co centre in a chelating mode, whereas the 5-nitro­isophthalate and acetate ions are bonded to two different Co atoms. The crystal structure is stabilized by O—H⋯O hydrogen bonds.

Poly[di-μ2-acetato-diaquabis(2,2′-bipyridine)bis(μ3-5-nitroisophthalato)tricobalt(II)]

Poly[di-μ₂-acetato-diaquabis(2,2′-bipyridine)bis(μ₃-5-nitroisophthalato)tricobalt(II)]