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In the structure of the title complex, [Cu(C 8 H 4 O 4 )(C 12 H 8 N 2 )(H 2 O)]·C 3 H 7 NO, the Cu II  ion is penta­coordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and a water O atom located at the apical site. The structure displays O—H⋯O hydrogen bonding and inter­molecular π–π stacking inter­actions between 1,10-phenantroline ligands [inter­planar distance of 3.448 (5) Å].

acta crystallographica. section e

Aqua(3-formyl-2-oxidobenzoato-κ2O1,O2)(1,10-phenanthroline-κ2N,N′)copper(II) dimethylformamide solvate