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The asymmetric unit of the title compound, [Co 2 (C 10 H 2 O 4 S 3 ) 2 (C 12 H 8 N 2 ) 4 ]·2C 3 H 7 NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octa­hedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2- b :2′,3′- d ]thio­phene-2,6-dicarb­oxy­l­ate anions. The anions act as bridges between the Co II  centers.

acta crystallographica. section e

Bis(μ-dithieno[3,2-b:2′,3′-d]thiophene-2,6-dicarboxylato-κ2O2:O6)bis[bis(1,10-phenanthroline-κ2N,N′)cobalt(II)] dimethylformamide disolvate