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In the centrosymmetric title compound, [Ni(C 8 H 8 NO 3 S) 2 (H 2 O) 4 ], the Ni II  ion, which lies on an inversion centre, is six coordinated by four water mol­ecules and two propionate O atoms from two 2-pyridylsulfanylpropionate N-oxide ligands, forming a slightly distorted octa­hedral geometry. An intra­molecular O—H⋯O hydrogen bond stabilizes the mol­ecular conformation. The crystal packing is consolidated by inter­molecular O—H⋯O and C—H⋯O hydrogen bonding.

Tetraaquabis[3-(2-pyridylsulfanyl)propionatoN-oxide]nickel(II)