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In the title compound, [Cu(C 20 H 12 Br 2 N 2 O 2 )(CH 3 OH)], the Cu II  ion, and the C, O and hydr­oxy H atoms of the coordinated methanol mol­ecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu II  ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetra­dentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into extended chains along [001].

acta crystallographica. section e

{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ4O,N,N′,O′}(methanol-κO)copper(II)