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In the title compound, [Zn 2 (C 22 H 36 NS 2 ) 4 ], two bidentate dithio­carbamate groups chelate directly to the Zn II  atoms, whereas the two remaining dithio­carbamate ligands bridge the Zn atoms  via  a crystallographic inversion centre. The Zn atoms show a strongly distorted tetra­hedral geometry. Adding the long S⋯S distance with the inversion centre being in the middle, the resulting five-coordinate geometry around the Zn atoms can be considered to be between distorted recta­ngular pyramidal and trigonal bipyramidal, with a calculated τ value of 0.31. In this dimer complex, two inversion-related tetra­decyl carbon chains exhibit all- trans  conformations, and the other two chains show a  cis  conformation at the end of the chains.

acta crystallographica. section e

Bis(μ-N-benzyl-N-tetradecyldithiocarbamato-κ2S:S′)bis[(N-benzyl-N-tetradecyldithiocarbamato-κ2S,S′)zinc(II)]