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In the title compound, C 9 H 10 N 2 O 4 S, which is an important inter­mediate for the preparation of anti­tumor platinum drugs, the dioxolane ring adopts an envelope conformation with the C atom bonded to the thienyl ring at the flap position. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds result in the formation of two five-membered rings having envelope conformations. In the crystal structure, inter­molecular N—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network.

(4S,5S)-2-(2-Thienyl)-1,3-dioxolane-4,5-dicarboxamide