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In the title compound, [Cu(C 7 H 4 N 3 O 2 ) 2 (C 3 H 7 NO)], the Cu II  atom is five-coordinated in a distorted square-pyramidal geometry, with the N atoms in equatorial positions and the dimethyl­formamide O atom in an axial position. The dihedral angle between adjacent benzene rings is 70.33 (12)°.

catena-Poly[[(dimethylformamide-κO)copper(II)]-bis(μ-4-nitrophenylcyanamido-κ2N1:N3)]

catena-Poly[[(dimethylformamide-κO)copper(II)]-bis(μ-4-nitrophenylcyanamido-κ²N¹:N³)]