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The title compound, [Ag(NO 3 )(C 20 H 30 S 2 )]  n  , was synthesized by the reaction of silver nitrate and 1,4-bis­(cyclo­hexyl­thio­meth­yl)benzene (bctmb) in acetonitrile. The coordination polymer exhibits a two-dimensional layer structure. The layers are wave-like and parallel to the crystallographic  ac  plane; Ag I  ions are linked by the bctmb ligands and nitrate anions along the crystallographic  a  and  c  directions, respectively. In addition, the crystal structure is stabilized by C—H⋯O hydrogen bonds.

acta crystallographica. section e

Phyllo-poly[[μ2-1,4-bis(cyclohexylsulfanylmethyl)benzene-κ2S:S′](μ2-nitrato-κ2O:O′)silver(I)]