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The title mol­ecule, C 12 H 14 ClN 2 O 3 PS, has a  cis  configuration with respect to the C=N bond. Inter­molecular C—H⋯O inter­actions inter­connect the mol­ecules into chains along the  c  axis. The chains are further connected into a two-dimensional network parallel to the  bc  plane by weak π–π inter­actions between adjacent aromatic rings (centroid–centroid distance = 3.772Å).

O,O′-Diethyl {(Z)-[(2-chlorophenyl)(cyano)methylene]aminooxy}thiophosphonate