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In the title compound, [Cu(2)(C(10)H(12)O(4))(C(12)H(8)N(2))(2)(H(2)O)(2)](BF(4))(2)·H(2)O, the two Cu atoms are each chelated by the acetyl-acetonate unit of the 3,4-diacetyl-hexa-2,4-diene-2,5-diolate (tae) ligand. The Cu atoms are square-pyramidally penta-coordinated, with one bidentate 1,10-phenanthroline (phen) and the tae ligand basal and one water mol-ecule apical. The pyridyl rings of the phen ligands participate in π-π [centroid-centroid distance = 3.894 (3) Å] and C-H ⋯ π inter-actions, generating layers which are inter-connected through O-H⋯O and O-H⋯F hydrogen bonds between the water mol-ecules and the tetra-fluorido-borate anions. The F atoms of both tetra-fluorido-borate anions are each disordered over two positions of equal occupancy.

acta crystallographica. section e

(μ-3,4-Diacetylhexa-2,4-diene-2,5-diolato-κ4O2,O3:O4,O5)bis[aqua(1,10-phenanthroline-κ2N,N′)copper(II)] bis(tetrafluoridoborate) monohydrate