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The mol­ecule of accanthomine A, C 15 H 13 N 5 , is approximately planar, with the indolyl fused-ring and the pyrimidyl ring being twisted by 31.7 (1)° The amino group of the five-membered ring is an intramolecular hydrogen-bond donor to a nitro­gen acceptor of the pyrimide ring. The amino group of the pyrimide ring is a hydrogen-bond donor to the N atoms of adjacent mol­ecules. These hydrogen-bonding inter­actions give rise to a layered network with a 4.8 2  topology.

4-(3,4-Dihydro-β-carbolin-1-yl)pyrimidin-2-amine