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The title compound, C 10 H 8 O 2 , is a precursor to an unusual bis-homoaromatic dication and to heterodiamantanes and other oxa-cage compounds. Two independent mol­ecules, each of which is situated on a center of symmetry, comprise the unit cell. Both mol­ecules are in nearly identical chair conformations.

anti-Tricyclo[4.2.1.12,5]deca-3,7-diene-9,10-dione

anti-Tricyclo[4.2.1.1^2,5]deca-3,7-diene-9,10-dione