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In the title compound, C 13 H 9 N 3 O 2 ·C 3 H 7 NO, the benzimidazole ring system and the benzene ring are essentially coplanar, forming a dihedral angle of 0.86 (5)°. The crystal packing is stabilized by an inter­molecular N—H⋯O hydrogen bond and a π–π stacking inter­action with a centroid–centroid separation of 3.685 (4) Å.

1-(1H-Benzimidazol-2-yl)-4-nitrobenzene dimethylformamide solvate