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The structure of the title compound, [Fe 2 (C 17 H 16 N 2 O 2 ) 2 (OH) 2 ]·2C 3 H 7 N, consists of centrosymmetric dimeric units in which crystallographically equivalent Fe III  ions are doubly bridged by hydroxide groups. Each Fe III  center in the complex has a six-coordinated distorted  cis -FeN 2 O 4  octa­hedral geometry.

Di-μ-hydroxido-bis({2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}iron(III)) dimethylformamide disolvate