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The title compound, [CuI(C 19 H 20 Br 2 N 2 )], lies across a crystallographic mirror plane. The coordination around the copper centre is distorted trigonal planar, with a bite angle of 94.7 (3)°. A six-membered chelate ring in a chair conformation is formed by the coordination of the imine N atoms of the bidentate ligand to the Cu I  atom. This conformation is required by the crystallographic mirror symmetry. The inter­planar angle between the benzene rings is 74.85 (19)°. The crystal structure exhibits weak inter­molecular C—H⋯π inter­actions, which link the mol­ecules into chains along the  b  axis.

[N,N′-Bis(4-bromobenzylidene)-2,2-dimethylpropane-κ2N,N′]iodidocopper(I)

[N,N′-Bis(4-bromobenzylidene)-2,2-dimethylpropane-κ²N,N′]iodidocopper(I)