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In the title compound, [Co(C 6 H 4 N 5 ) 2 (H 2 O) 2 ], the Co atom is bonded to two water mol­ecules and two bidentate 5-(2-pyrid­yl)tetra­zolate ligands resulting in a slightly distorted octa­hedral CoN 4 O 2  coordination geometry. The Co II  cation is situated on a crystallographic center of inversion. The asymmetric unit therefore comprises one-half of the mol­ecule. The four N atoms belonging to two bidentate 5-(2-pyrid­yl)tetra­zolate ligands lie in the equatorial plane and the two associated water mol­ecules are observed in the axial coordination sites. The crystal structure exhibits a three-dimensional supra­molecular network assembled by inter­molecular O—H⋯N hydrogen bonds.

Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ2N1,N5]cobalt(II)

Diaquabis[5-(2-pyridyl)-1H-tetrazolato-κ²N¹,N⁵]cobalt(II)