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The title complex, [RuCl(2)(C(25)H(26)N(2))]·CH(2)Cl(2), is best thought of as containing an octa-hedrally coordinated Ru center with the arene occupying three sites. Two Ru-Cl bonds and one Ru-carbene bond complete the distorted octa-hedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the C(6)H(2)(CH(3))(3) arene group by a CH(2) bridge. This leads to a system with very little apparent strain. A dichloro-methane solvent mol-ecule completes the crystal structure. Further stabilization is accomplished via C-H⋯N and C-H⋯Cl interactions.

acta crystallographica. section e

Dichlorido[1-(2-methylbenzyl)-3-(η<sup>6</sup>-2,4,6-trimethylbenzyl)-1<i>H</i>-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate

Dichlorido[1-(2-methylbenzyl)-3-(η6-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate

Dichlorido[1-(2-methylbenzyl)-3-(η⁶-2,4,6-trimethylbenzyl)-1H-2,3-dihydrobenzimidazol-2-ylidene]ruthenium(II) dichloromethane solvate