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In the title mol­ecule, C 24 H 20 P 2 S, the P—P bond length is 2.2263 (5) Å. The two phenyl rings attached to the three- and five-coordinated P atoms, respectively, form dihedral angles of 56.22 (5) and 71.74 (5)°.

1,1,2,2-Tetraphenyl-1λ5-diphosphane 1-sulfide

1,1,2,2-Tetraphenyl-1λ⁵-diphosphane 1-sulfide