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In the title ion-pair, C 22 H 29 Cl 2 N 4 O 2+ ·C 2 F 3 O 2− , ammonium–carboxyl­ate N—H⋯O hydrogen bonds link two cations and two anions about a centre of inversion to generate a hydrogen-bonded tetramer. In the cation, one of the imino N atoms is protonated and donates a hydrogen bond to the O atom of the adjacent chloro­phenyl ring. The other imino N atom acts as a hydrogen-bond acceptor from a phenolate O atom.

2-{1-[2-((2-Ammonioethyl){2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate trifluoroacetate