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In the toluene hemisolvated tripodal tris­(2-amino­ethyl)amine Schiff base, C 30 H 33 Cl 3 N 4 O 3 ·0.5C 7 H 8 , one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent mol­ecule is disordered about a centre of inversion.

2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxyphenyl)ethylideneamino]ethyl}amino)ethyliminio]ethyl}-4-chlorophenolate toluene hemisolvate