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In the title compound, C 2 H 6 NO 2+ ·C 4 H 3 O 4− ·C 2 H 5 NO 2 ·H 2 O, the asymmetric unit contains two glycine residues, one protonated and one in the zwitterionic form, a hydrogen fumarate anion and a water mol­ecule. Through N—H⋯O and O—H⋯O hydrogen bonds, mol­ecules assemble in layers parallel to the (10    ) plane, one layer of hydrogen fumarate anions alternating with two layers of glycine mol­ecules. In each glycine layer, hydrogen bonds generate an  R44 (19) graph-set motif. Further hydrogen bonds involving the water mol­ecule and the hydrogen fumarate anions result in the formation of a three-dimensional network.

Glycinium hydrogen fumarate glycine solvate monohydrate